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<p><b>E-school&nbsp; di&nbsp; <a href="../index.htm">Arrigo
Amadori</a><br>
<br>
<font size="4">Sintesi<br>
<br>
</font><u><font size="5">Teoria atomica</font></u></b>
<br>
<br>
<b>01 - L'atomo.</b><br>
<br>
La materia è costituita da atomi. Un atomo è composto da un <b>nucleo</b>
elettricamente carico <b>positivamente</b><br>
e da un certo numero di <b>elettroni</b>, carichi negativamente, che gli ruotano
attorno.&nbsp;<br>
<br>
Il nucleo è composto da <b>protoni</b>, che sono particelle cariche
positivamente e da <b>neutroni</b> che sono particelle<br>
prive di carica.&nbsp;<br>
<br>
La massa di un protone è circa uguale alla massa di un neutrone ed entrambi
sono circa 2000 volte più<br>
pesanti di un elettrone. E' per questo che sono gli elettroni che ruotano
attorno al nucleo (molto più pesante)<br>
e non viceversa. Il nucleo è molto pesante e &quot;concentrato&quot; mentre gli
elettroni sono molto leggeri e mobili.<br>
<br>
Normalmente, il numero degli elettroni che ruotano attorno al nucleo <b>eguaglia</b>
il numero dei protoni che&nbsp;<br>
costituiscono il&nbsp;nucleo. Essendo dette cariche di valore uguale (a parte il
segno), un atomo è normalmente&nbsp;<br>
elettricamente&nbsp;<b>neutro</b>. Per questo motivo (e per fortuna, altrimenti
i corpi sarebbero sbalzati in tutte le&nbsp;<br>
direzioni, essendo&nbsp;la forza elettrica piuttosto forte) la materia è
normalmente elettricamente neutra.<br>
<br>
La materia, anche se appare densa e &quot;dura&quot;, è in effetti praticamente
<b>vuota</b>. Se, facendo le proporzioni,&nbsp;<br>
consideriamo il nucleo grande come una mela, gli elettroni gli ruotano attorno
ad una distanza pari a circa<br>
un chilometro. Questo fatto è di estrema importanza e, se in qualche modo,
riuscissimo ad eliminare&nbsp;<br>
tutto questo spazio, riusciremmo a &quot;compattare&quot; tutta la massa in uno
spazio molto piccolo raggiungendo<br>
densità enormi. Questo è ciò che succede nei buchi neri e nelle stelle di
neutroni in cui, per esempio, tutta<br>
la enorme massa di una stella viene compattata in uno spazio di pochi chilometri
cubi.<br>
<br>
Un atomo è quindi composto da un nucleo formato da nucleoni (protoni e
neutroni) e da elettroni (in egual<br>
numero dei protoni, quando l'atomo è elettricamente neutro) che gli ruotano
attorno. Ogni atomo è indicato &nbsp;<br>
da una sigla e da due numeri : il <b>numero atomico</b> (il numero dei protoni
identico al numero degli elettroni) ed&nbsp;<br>
il&nbsp;<b>numero di massa</b> (il numero dei nucleoni, ovvero dei protoni e dei
neutroni che costituiscono il nucleo).<br>
Il numero dei neutroni è dato, ovviamente, dal numero di massa - il numero
atomico.<br>
<br>
Esempio (atomo dell'elio) :<br>
<br>
&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; <img src="005.gif" border="0" width="330" height="203"><br>
<br>
Un atomo può esistere in natura con un ugual numero atomico ma diverso numero
di massa. Simili atomi&nbsp;<br>
sono detti <b>isotopi</b> ed hanno le stesse proprietà chimiche (cioè di
creare composti, molecole, dalle stesse&nbsp;<br>
proprietà). Un esempio di ciò è l'atomo di <b>idrogeno</b>. In natura esso è
presente in grande maggioranza&nbsp;<br>
formato da un protone ed un elettrone che gli ruota attorno. Vi è però, in
minore quantità, anche il <b>deuterio</b><br>
che è formato da un protone, un neutrone ed un elettrone. Con esso si forma
l'acqua pesante. Vi è anche&nbsp;<br>
il <b>trizio</b> (più raro) formato da un protone, due neutroni ed un
elettrone. Chimicamente, idrogeno, deuterio&nbsp;<br>
e trizio hanno le stessa proprietà (in quanto hanno lo stesso numero di protoni
ed elettroni). Riassumendo :<br>
<br>
&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; <img src="006.gif" border="0" width="330" height="203"><br>
<br>
Gli atomi esistenti un natura sono circa 90 e sono elencati in una tavola, detta
tavola periodica degli elementi&nbsp;<br>
o tavola di Mendeleyev :<br>
<br>
&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; <a href="http://www.apsidium.com/ext_pt/expertab.htm" target="_blank">http://www.apsidium.com/ext_pt/expertab.htm</a><br>
<br>
<b>02 - Legami chimici</b><br>
<br>
Gli atomi alla sinistra di questa tavola sono detti <b>metalli</b> ed hanno la
proprietà di <b>perdere</b> elettroni diventando<br>
<b>ioni</b> <b>positivi</b>. Gli atomi posti alla destra, invece, sono detti <b>non
metalli</b> ed hanno la proprietà di acquistare<br>
elettroni, cioè di diventare<b> ioni negativi</b>. Gli altri atomi hanno
proprietà di perdere od acquistare elettroni&nbsp;<br>
in maniera meno netta. Certi atomi si possono addirittura comportare da metalli
o da non metalli a seconda<br>
dei casi.<br>
<br>
L'attitudine che hanno gli atomi di acquistare o perdere elettroni fa si che si
formino <b>legami elettrici</b> fra gli stessi<br>
ed è così che si formano le <b>molecole</b>, i costituenti fondamentali dei
composti chimici di cui è fatta la materia.<br>
<br>
Il tipo più semplice di legame che si instaura fra gli atomi è il cosiddetto <b>legame
ionico</b>. E' il caso del sale da&nbsp;<br>
cucina, il cloruro di sodio NaCl. In esso il sodio diventa uno ione positivo ed
il cloro uno ione negativo.&nbsp;<br>
Questi ioni si attraggono elettricamente e si forma un reticolo cristallino
regolare :<br>
<br>
&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; <img src="007.gif" border="0" width="330" height="203"><br>
<br>
Altri tipo di legami chimici sono basati sul fatto che gli elettroni vengono <b>condivisi</b>
dagli atomi che&nbsp;<br>
costituiscono il legame. Si tratta del <b>legame covalente</b>.<br>
<br>
E' molto interessante il caso dell'<b>acqua</b> :<br>
<br>
&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; <img src="008.gif" border="0" width="330" height="203"><br>
<br>
Gli elettroni sono condivisi dall'atomo di ossigeno e dai due atomi di idrogeno
in modo <b>asimmetrico</b>.<br>
Gli elettroni tendoni a stare più dalla parte dell'ossigeno e per questo motivo
la molecola di acqua si&nbsp;<br>
comporta come un <b>dipolo</b> elettrico, ovvero un oggetto dotato di polarità
elettrica.<br>
<br>
Se immergiamo, per esempio, del sale da cucina nell'acqua, i dipoli dell'acqua
scompongono il reticolo<br>
del sale inserendosi fra gli ioni Na e Cl facendo sì che il sale si <b>sciolga</b>
(pur mantenendosi i legami fra<br>
sodio e cloro).<br>
<br>
Se poi inseriamo due <b>elettrodi</b> nella soluzione collegati ad una batteria,
si ha il fenomeno dell'<b>elettrolisi</b> :&nbsp;<br>
gli ioni sciolti in acqua tenderanno ad andare, rompendo i legami, verso gli
elettrodi dotati di segno&nbsp;<br>
contrario.<br>
<br>
&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; <img src="009.gif" border="0" width="330" height="203"><br>
<br>
Gli ioni di sodio, positivi, tenderanno ad andare verso l'elettrodo negativo, il
catodo, e gli ioni di cloro,&nbsp;<br>
negativi,&nbsp;renderanno ad andare verso l'elettrodo positivo, l'anodo. In
questo modo si rompono i legami&nbsp;<br>
chimici fra&nbsp;sodio e cloro ed agli elettrodi si vanno a depositare i
suddetti atomi (almeno teoricamente,&nbsp;<br>
perché nella realtà le cose sono sempre più complicate, per cui,&nbsp;in
effetti, al catodo si sviluppa idrogeno !).<br>
<br>
<b>03 - Gli stati della materia.</b><br>
<br>
La materia si presenta in vari <b>stati</b>..<br>
<br>
Se i <b>legami</b> elettrici fra le molecole sono <b>forti</b>, la materia si
presenta allo stato <b>solido</b> e le molecole sono&nbsp;<br>
disposte in modo da&nbsp;formare un <b>reticolo</b> (che può essere regolare od
irregolare (amorfo)). Le molecole&nbsp;<br>
oscilleranno così&nbsp;attorno a punti geometrici fissi senza allontanarsi
significativamente da essi.<br>
<br>
Se i legami elettrici fra le molecole sono <b>meno forti</b>, si ha lo stato <b>liquido</b>.
In questo stato, i legami sono<b><br>
</b>meno forti rispetto allo stato solido ma sufficientemente forti da
costringere il liquido (a causa della gravità)&nbsp;<b><br>
</b>in un recipiente. In questo caso non si ha un reticolo e le molecole hanno
la possibilità di traslare disordinatamente&nbsp;<b><br>
</b>senza però abbandonare il liquido (se non in maniera sporadica
(evaporazione)).<br>
<br>
Se i legami elettrici fra le molecole sono deboli o quasi assenti, si ha lo
stato gassoso. Le molecole sono<b><br>
</b>libere di muoversi ed andare in qualunque punto disponibile dello spazio.<br>
<br>
<b>04 - Modelli atomici.</b><br>
<br>
In questo paragrafo descriviamo brevemente i <b>modelli atomici</b> più
importanti che storicamente&nbsp;<br>
sono stati proposti.<br>
<br>
L'ipotesi che la materia sia formata da atomi risale a <b>Democrito</b> (400
a.c.). Atomo, in greco,<br>
significa &quot;non divisibile&quot;. L'idea atomistica fu però avversata da <b>Aristotele</b>
che, successivamente,&nbsp;<br>
divenne il filosofo &quot;ufficiale&quot; della chiesa. Per questo motivo
dobbiamo aspettare addirittura&nbsp;fino&nbsp;<br>
al 1800 perché gli scienziati riprendessero in considerazione l'ipotesi
atomica.<br>
<br>
Nel 1803 <b>Dalton</b> spiegò i ben noti fenomeni chimici secondo i quali le
sostanze sono formate dai&nbsp;<br>
loro componenti secondo rapporti ben precisi fra numeri interi, ipotizzando che
la&nbsp;materia fosse&nbsp;<br>
costituita da atomi.&nbsp;<br>
<br>
Con la scoperta della <b>radioattività naturale</b>, si capì successivamente
che gli atomi non erano<br>
particelle indivisibili, essi erano composti da parti più piccole.<br>
<br>
Nel 1898 <b>Thomson</b> propose il primo modello fisico dell'atomo. Egli immaginò
che un atomo&nbsp;<br>
fosse costituito da una sferetta di materia caricata positivamente (protoni e
neutroni non erano&nbsp;<br>
stati ancora scoperti) in cui gli elettroni negativi (da poco scoperti) erano
immersi.&nbsp;&nbsp;&nbsp;<br>
<br>
&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; <img src="1.gif" border="0" width="330" height="203"><br>
<br>
Nel 1911 <b>Rutherford</b> fece un esperimento cruciale per mettere alla prova
il modello di Thomson.<br>
Bombardò un sottilissimo foglio di <b>oro</b> con raggi alfa (atomi di elio
completamente ionizzati, ciò&nbsp;<br>
privati degli elettroni). L'esperimento portò alla constatazione che i raggi
alfa non erano quasi mai&nbsp;<br>
deviati. Essi attraversavano il foglio di oro senza quasi mai esserne
disturbati. Solo alcuni raggi&nbsp;<br>
alfa (1 %) erano deviati dal foglio&nbsp;di oro e lo erano in modo notevole
(alcuni, addirittura, venivano&nbsp;<br>
completamente. respinti).&nbsp;<br>
<br>
Sulla base di questo fondamentale esperimento, Rutherford propose un modello di
atomo in&nbsp;<br>
cui quasi tutta la massa dell'atomo è concentrata in una porzione molto
piccola, il cosiddetto<br>
nucleo (caricato positivamente) e gli elettroni gli ruotano attorno così come i
pianeti ruotano<br>
attorno al sole.<br>
<br>
&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; <img src="2.gif" border="0" width="330" height="203"><br>
<br>
Il nucleo è così concentrato che gli elettroni gli ruotano attorno a distanze
relative enormi.&nbsp;<br>
<br>
Il modello di Rutherford ha però un grande &quot;difetto&quot; che lo mette in
crisi. Secondo la&nbsp;<br>
teoria elettromagnetica una carica in movimento accelerato (non in moto
rettilineo uniforme)<br>
emette <b>onde elettromagnetiche</b> e quindi perde energia. Per questo motivo,
gli elettroni<br>
dell'atomo di Rutherford, perché ruotano su orbite circolari, dovrebbero
emettere onde&nbsp;<br>
elettromagnetiche e quindi, perdendo energia, <b>cadere</b> nel nucleo cosa che
invece non&nbsp;<br>
accade, perché gli atomi sono oggetti molto stabili (la materia appare
normalmente&nbsp;<br>
stabile).<br>
<br>
Nel 1913 <b>Bohr</b> propose una modifica concettuale al modello di Rutherford.
Pur accettandone<br>
l'idea di &quot;modello planetario&quot;, postulò che gli elettroni avessero a
disposizione <b>orbite di &quot;parcheggio&quot;</b><br>
fisse nelle quali non emettono né assorbono energia. Un elettrone emette od
assorbe energia&nbsp;<br>
elettromagnetica sotto forma di onde elettromagnetiche solo se <b>&quot;salta&quot;</b>
da un'orbita all'altra.&nbsp;<br>
<br>
Questa idea, non compatibile con le leggi della fisica classica (di Newton), si
basa sulle idee della&nbsp;<br>
nascente <b>meccanica quantistica</b>.<br>
<br>
Il modello di Bohr spiegava molto bene l'atomo di idrogeno ma non quelli più
complessi. <b>Sommerfeld</b>&nbsp;<br>
propose allora una correzione al modello di Bohr secondo la quale si aveva una
buona corrispondenza&nbsp;<br>
fra la teoria e le osservazioni degli <b>spettri</b> degli atomi (uno spettro è
l'insieme delle frequenze delle<br>
radiazioni elettromagnetiche emesse o assorbite dagli elettroni di un atomo).&nbsp;<br>
<br>
Successivamente, si pervenne ad un modello atomico più coerente ai grandi
progressi che la&nbsp;<br>
meccanica&nbsp;quantistica nel frattempo aveva fatto.<br>
<br>
Nel 1930 fu scoperto il <b>neutrone</b> per cui si pervenne presto ad un modello
dell'atomo pressoché<br>
completo in cui al centro vi è il nucleo composto di protoni (positivi) e
neutroni (protoni e neutroni&nbsp;<br>
si chiamano collettivamente nucleoni) ed attorno vi&nbsp;ruotano gli elettroni.&nbsp;<br>
<br>
Anche l'idea di <b>come</b> gli elettroni ruotano attorno al nucleo venne
profondamente modificata alla&nbsp;<br>
luce delle scoperte della meccanica quantistica.&nbsp;<br>
<br>
Fu abbandonato il concetto di orbita e fu introdotto il concetto di <b>orbitale</b>.<br>
<br>
Secondo la meccanica quantistica&nbsp;un elettrone <b>non</b> è descrivibile in
termini di <b>traiettoria</b>. Non&nbsp;<br>
si può quindi affermare con certezza dove un elettrone si trova in un certo
istante né dove si&nbsp;<br>
troverà in un&nbsp;istante successivo. Si può solo conoscere la <b>probabilità</b>
di trovare l'elettrone in&nbsp;<br>
un certo punto&nbsp;dello spazio.<br>
<br>
Un orbitale non è una traiettoria in cui un elettrone (secondo le idee della
fisica classica) può&nbsp;<br>
stare, è&nbsp;invece una &quot;<b>nuvoletta&quot; di probabilità</b> in cui si
può trovare l'elettrone.<br>
<br>
Esempi di orbitali per l'atomo di idrogeno dove maggiore luminosità significa
maggiore probabilità&nbsp;<br>
di trovare l'elettrone (in sezione) :<br>
<br>
<img src="3.gif" border="0" width="300" height="300"><img src="4.gif" border="0" width="300" height="300"><br>
<br>
<img src="6.gif" border="0" width="300" height="300"><img src="8.gif" border="0" width="300" height="300"><br>
<br>
&nbsp; <img src="7.gif" border="0" width="300" height="300"><br>
<br>
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<br>
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